Instantaneous
dipoles in other symmetrical molecules |
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Symmetrical molecules such as O2, N2, Cl2, F2 and H2 have pure-covalent intermolecular bonding. Electrons are shared evenly so the molecule has no permanent dipole. Lets look at a simple hydrogen molecule. Look at the animation on the right and you will see the electrons shared evenly. | |
But sometimes the random nature of the electron's movement may cause an uneven distribution of electrons inside the molecule. This leads to the molecule becoming polar for an instant. Once again dispersion forces act between the molecules.
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Since dispersion forces depend on random movement of electrons it makes sense to assume that the more electrons present in the molecule the greater the chance of the formation of instantaneous dipoles. The greater the frequency of instantaneous dipole formation the greater the strength of the dispersion forces. Since melting temperature is
an indication of intermolecular bonding strength, place the following
molecules in order of increasing melting temperature. N2, Cl2,
F2, O2, I2 and H2 Why is CCl4 a liquid
at room temperature but I2 is a solid? Click
to hide solution H2> N2> O2> F2 > Cl2> I2 Click
to hide solution
I2 is a bigger molecule than CCl4 . I2 has 104 electrons but CCl4 has 74 electrons.
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