Naming haloalkanes
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Hydrocarbons in which one or more hydrogens are replaced by one or more halogens are known as haloalkanes. Cl = Chloro |
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Naming them is s straight forward procedure if we follwo the steps below. | |
Step 1 We identify the longest carbon chain in the molecule.
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Examples 1 The compound is thus named 1-bromo-2-chloroethane |
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Examples 1 The compound is thus named 1,2-dibromo-3-fluorobutane |
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The compound is thus named 3,4-dibromo-1,2-difuoro-1-iodobutane as this gives the lowest sum of carbons 3 + 4 + 1+ 2 + 1 = 11. If we had numbered the carbons from the right the name would have been 1,2-dibromo-3,4-difuoro-4-iodobutane and this would have given the highest sum of carbons 1 + 2 +3 + 4+ 4 = 14. |
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Now see if you can name the compound on the right. Whether we number the carbons from left to right or right to left it doesnt matter we still get the same total (15) . Hence we go by alphabetical order of the halogens. |