Volumemetric analysis (2009 NSW HSC)


1) The nitrogen content of bread was determined using the following procedure:
• A sample of bread weighing 2.80 g was analysed.
• The nitrogen in the sample was converted into ammonia.
• The ammonia was collected in 50.0 mL of 0.125 mol L−1 hydrochloric acid. All of the ammonia was neutralised, leaving an excess of hydrochloric acid.
The excess hydrochloric acid was titrated with 23.30 mL of 0.116 mol L−1 sodium hydroxide solution.
(a) Write balanced equations for the TWO reactions involving hydrochloric acid.

Solution
(b) Calculate the moles of excess hydrochloric acid.

Solution
(c) Calculate the moles of ammonia.

Solution

(d) Calculate the percentage by mass of nitrogen in the bread.

Solution