Gravimetric analysis 2013 VCE

 

1) The strength of the eggshell of birds is determined by the calcium carbonate, CaCO3, content of the eggshell.
The percentage of calcium carbonate in the eggshell can be determined by gravimetric analysis.
0.412 g of clean, dry eggshell was completely dissolved in a minimum volume of dilute hydrochloric acid.


An excess of a basic solution of ammonium oxalate,
(NH4)2C2O4, was then added to form crystals of
calcium oxalate monohydrate, CaC2O4.H2O.
The suspension was filtered and the crystals were then dried to constant mass.
0.523 g of CaC2O4.H2O was collected.
a. Write a balanced equation for the formation of the calcium oxalate monohydrate precipitate.

Solution

b. Determine the percentage, by mass, of calcium carbonate in the eggshell.

Solution