Volumetric analysis

exercise 10

Irene is given 200ml of 0.2M HCl solution. Her friend accidentally drops in some solid NaOH which quickly dissolves. A 20ml aliquot is taken and titrated against a 0.1M NaOH solution. The results are shown on the right.

Calculate the mass of NaOH accidentally dropped in to the 200ml solution.

Atomic mass Na =23, O =16, H=1

 
Volume
Start
12.40 mls
Finish
32.22 mls
Total

The equation for the reaction is shown below.

Step 1 Calculate the mole of sodium hydroxide added
Mole = volume X concentration

Step 2 Using the equation calculate the number of mole of acid required to react completely

Step 3 Find the mole of acid that should have been present in the 20ml aliquot of a 0.2M solution
Mole= volume X concentration

Step 4 Find the mole of acid that reacted with the NaOH which was accidentally dropped in to the solution. This will equal to the mole of NaOH that was added.

Step 5 Calculate the mass of NaOH added.

 

Solution

Exercises

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