Volumetric analysis

exercise 7

 
Volume
Start
15.40 mls
Finish
32.22 mls
Total
16.82 mls

A 0.15gram sample of hydrated sodium carbonate was dissolved in 20 mls of water. The solution was then titrated against a 0.2M HCl solution. The result is shown on the left.

What mass of the sample is due to water?

( Atomic mass of Na = 23, H = 1, O =16, C =12)

The equation for the reaction is shown below.

Step 1 Calculate the mole of substance delivered from the burette. In this case HCl solution
Mole = Average Volume(litres) X Concentration
Mole of HCl = 0.0168 X 0.2 = 0.00336 mole

Step 2 Using the equation calculate the number of mole of sodium carbonate in the sample.
Mole of sodium carbonate = 0.00168 mole

Step 3 Find the mass of sodium carbonate present in the sample.
Mass of sodium carbonate = 0.00168 X 83 = 0.139 grams

Step 4 Calculate the mass of water in the sample.

Mass of water = 0.150 - 0.139 = 0.011 grams

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