Equilibrium
expression
|
|
So many important reactions involve equilibria that scientists have sought to find a mathematical expression they can apply in order to provide the right conditions to best manipulate these reactions. A mathematical expression was found that gives a constant value, at the same temperature, when the system has reached equilibrium. The expression is given below and is known as the reaction quotient or equilibrium expression.
Now the reaction quotient has different values as the reaction proceeds, depending on the mixture of substances in the reaction vessel. Is is only when the system reaches equilibrium that the value of the reaction quotient remains constant at a value known as the equilibrium constant (Kc). |
|
K, the reaction quotient, is equal to Kc only when the system has reached equilibrium. |
Click to see the equilibrium expression for the combustion of ethane form from the equation given on the left.
|
But
what does the equilibrium constant tell us about the reaction? |
|
Lets see how
we can use the mathematical expression of equilibria to calculate and
predict products and reaction conditions. |