Volumetric analysis

exercise 6

 
Volume
Start
10.40 mls
Finish
22.22 mls
Total
11.82 mls

A 0.600gram sample of impure NaOH was dissolved in 20 mls of water. The solution was then titrated against a 0.12M HCl solution.

What is the percentage composition of NaOH in the sample.

( Atomic mass of Na = 23, H = 1, O =16 )

The equation for the reaction is shown below.

Step 1 Calculate the mole of substance delivered from the burette. In this case HCl solution
Mole = Average Volume(litres) X Concentration
Mole of HCl = 0.0118 X 0.12 = 0.00142

Step 2 Using the equation calculate the number of mole of NaOH in the sample.
Mole of NaOH = 0.00142

Step 3 Find the mass of NaOH present in the sample.
Mass of NaOH = 0.00142 X 40 = 0.0568grams

Step 4 Calculate the percent of the mass due to NaOH.

0.0568 / 0.600 X 100 = 9.47%

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